Chapter 1
Hydrocarbons
Alkane/Alkene/Alkyne prep & reactions — Wurtz, Corey-House, Lindlar's, Birch, ozonolysis, Markovnikov, syn/anti selectivity.
AlkanesAlkenes
AlkynesStereo
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Chapter 2
SN1 · SN2 · E1 · E2
Substitution & elimination mechanisms, nucleophiles, bases, leaving groups, haloalkane reactions — Finkelstein, Swart's, Lucas, Williamson.
SN1/SN2E1/E2
NucleophilesLeaving Groups
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Chapter 3
Alcohols, Ethers & Grignard
LAH, NaBH₄, DIBAL-H, PCC oxidation, Williamson ether synthesis, Pinacol rearrangement, Grignard with all carbonyl partners.
AlcoholsEthers
GrignardPinacol
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Chapter 4
Reduction, Oxidation & Hydrolysis
Rosenmund, Stephen's, Birch (ring), MPV, Red P/HI, KMnO₄ (Baeyer's + cleavage), Wacker, Oxo process, periodate, hydrolysis of all functional groups.
LAH vs NaBH₄KMnO₄
WackerHydrolysis
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Chapter 5
Aromatic Compounds
Phenols (Kolbe–Schmidt, Reimer–Tiemann, Fries), EAS reactions, o/p & meta directors, aniline, diazonium (Sandmeyer, Balz–Schiemann, Gomberg, coupling).
PhenolsEAS
AnilineDiazoniumNitrobenzene
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Chapter 6
Aldehydes, Ketones & Carboxylic Acids
Carbonyl prep & reactions, Aldol, Cannizzaro, Perkin, Knoevenagel, Reformatsky, Wittig, haloform/iodoform, Beckmann & Hofmann rearrangements.
AldolCannizzaro
WittigHaloformBeckmann
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